Forwards Kylian Mbappe and Marcus Rashford each scored twice, sharing the top spot on the Champions League scoring charts after the first round of the 2025-2026 season.
With his goal against Napoli on 18/9, striker Erling Haaland shattered Ruud Van Nistelrooy's record for the fewest matches needed to reach 50 Champions League goals.
Man City secured a 2-0 victory against Napoli in their opening Champions League group stage match, but the night was marred by Kevin De Bruyne's early exit after just 26 minutes.
Virgil Van Dijk's goal in the second minute of stoppage time secured a 3-2 win for Liverpool against Atletico in their opening Champions League match of the 2025-2026 season.
Atletico Madrid manager Diego Simeone was sent off in stoppage time during their 3-2 Champions League loss to Liverpool after an altercation with home fans.